Kat Von D and Jesse James are engaged! KVD confirmed her relationship with Jesse just a few months after he finalized his divorce from Sandra Bullock in June ’10 following his scandalous cheatin’ spree. Kat gushed about her new fiance: “This is definitely something that I think we weren’t expecting, and it’s been great. There is no one else for me. He’s the one.”  Her huge four-carat-plus platinum and diamond ring hails from the Neil Lane archival collection with a center diamond surrounded by smaller diamonds accented with a delicate filigree pattern and scroll work. Here, she oozes edgy bookworm in these ultra-cool, retro-inspired wayfarer eyeglasses.  –rpuccia

Get a similar look now: Carrera 6160, $82 or Ray Ban RX5184, $98